All tracks written by David Bowie except as noted.
Disc one

"In the Heat of the Morning" – 3:02
"London Bye Ta Ta" – 2:36
"Karma Man" – 3:00
"Silly Boy Blue" – 6:08
Tracks 1 to 4 recorded for John Peel in Top Gear as "David Bowie and the Tony Visconti Orchestra," 13 May 1968, tracks 1-3 broadcast 26 May 1968.
"Let Me Sleep Beside You" – 3:17
"Janine" – 3:24
Tracks 5 and 6 recorded for D.L.T. (Dave Lee Travis Show) as "David Bowie and Junior's Eyes," 20 October 1969; neither track were broadcast.
"Amsterdam" (Jacques Brel) – 3:18
"God Knows I'm Good" – 3:36
"The Width of a Circle" – 5:21
"Unwashed and Somewhat Slightly Dazed" – 5:07
"Cygnet Committee" – 9:07
"Memory of a Free Festival" – 3:18
Tracks 7 to 12 recorded for The Sunday Show introduced by John Peel as "David Bowie and the Tony Visconti Trio (aka The Hype)," 5 February 1970, broadcast date 8 February 1970.
"Wild Eyed Boy from Freecloud" – 5:55
Track 13 recorded for Sounds Of The 70s: Andy Ferris as "David Bowie and the Tony Visconti Trio," 25 March 1970, broadcast date 6 April 1970.
"Bombers" – 3:19
"Looking for a Friend" – 3:34
"Almost Grown" (Chuck Berry) – 2:44
"Kooks" – 3:32
"It Ain't Easy" (Ron Davies) – 2:51
Tracks 14 to 18 recorded for In Concert: John Peel as "David Bowie and friends," 3 June 1971, broadcast date 20 June 1971.

Disc two

"The Supermen" – 2:51
"Eight Line Poem" – 2:56
Tracks 1 and 2 recorded for Sounds Of The 70s: Bob Harris by David Bowie with Mick Ronson, 21 September 1971, broadcast date 4 October 1971.
"Hang on to Yourself" – 2:50
"Ziggy Stardust" – 3:26
"Queen Bitch" – 2:59
"I'm Waiting for the Man" (Lou Reed) – 5:24
"Five Years" – 4:24
Tracks 3 to 7 recorded for Sounds Of The 70s: Bob Harris as "David Bowie and The Spiders from Mars", 18 January 1972, broadcast date 7 February 1972.
"White Light/White Heat" (Reed) – 3:48
"Moonage Daydream" – 4:58
"Hang on to Yourself" – 2:50
"Suffragette City" – 3:28
"Ziggy Stardust" – 3:24
Tracks 8 to 12 recorded for Sounds Of The 70s: John Peel as "David Bowie and The Spiders from Mars," 16 May 1972, broadcast date 23 May 1972.
"Starman" – 4:05
"Space Oddity" – 4:16
"Changes" – 3:29
"Oh! You Pretty Things" – 2:57
Tracks 13 to 16 recorded for Johnnie Walker Lunchtime Show as "David Bowie and The Spiders from Mars," 22 May 1972, broadcast date 5 June 1972–9 June 1972.
"Andy Warhol" – 3:14
"Lady Stardust" – 3:21
"Rock 'n' Roll Suicide" – 3:08
Tracks 17 to 19 recorded for Sounds Of The 70s: Bob Harris as "David Bowie and The Spiders from Mars," 23 May 1972, broadcast date 19 June 1972.